α-Zirconium phosphate supported metal–salen complex: synthesis, characterization and catalytic activity for cyclohexane oxidation
作者: Savita KharePriti ShrivastavaRajendra ChokhareJagat Singh KirarSwati Parashar
作者单位: 1Devi Ahilya University
刊名: Journal of Porous Materials, 2017, Vol.24 (4), pp.855-866
来源数据库: Springer Journal
DOI: 10.1007/s10934-016-0325-6
关键词: Α-zirconium phosphateMn(Salen)Fe(Salen)OxidationCyclohexaneTert -butylhydroperoxide
英文摘要: Metal–salen intercalated α-zirconium phosphate, abbreviated as {α-ZrP·M(Salen), where M = Fe(III) and Mn(II)} was synthesized insitu by the flexible ligand method. The structure of resulting compounds was characterized by BET surface area, powder X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray analysis, X-ray photoelectron spectroscopy, thermogravimetric analysis and UV–visible spectroscopy. The catalytic activity of α-ZrP·M(Salen) was tested for the oxidation of cyclohexane using dry tert -butylhydroperoxide as an oxidant. In the oxidation reaction, cyclohexane was oxidized to cyclohexanol (A), cyclohexanone (K) and some unidentified products. It was found that the reactivity of α-ZrP·Fe(Salen) is greater than...
原始语种摘要: Metal–salen intercalated α-zirconium phosphate, abbreviated as {α-ZrP·M(Salen), where M = Fe(III) and Mn(II)} was synthesized insitu by the flexible ligand method. The structure of resulting compounds was characterized by BET surface area, powder X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray analysis, X-ray photoelectron spectroscopy, thermogravimetric analysis and UV–visible spectroscopy. The catalytic activity of α-ZrP·M(Salen) was tested for the oxidation of cyclohexane using dry tert -butylhydroperoxide as an oxidant. In the oxidation reaction, cyclohexane was oxidized to cyclohexanol (A), cyclohexanone (K) and some unidentified products. It was found that the reactivity of α-ZrP·Fe(Salen) is greater than...
全文获取路径: Springer  (合作)
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影响因子:1.348 (2012)

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关键词翻译
关键词翻译
  • cyclohexane 环己烷
  • catalytic 催化的
  • supported 支承的
  • phosphate 磷酸盐
  • synthesis 合成
  • catalyst 催化剂
  • reaction 反酌
  • oxidation 氧化
  • cyclohexanone 环己酮
  • cyclohexanol 环己醇