Hydrothermal synthesis of Ni 2 P nanoparticle and its hydrodesulfurization of dibenzothiophene
作者: Qi ZhaoYang HanXiang HuangJinhui DaiJintao TianZhibin ZhuLi Yue
作者单位: 1Ocean University of China
刊名: Journal of Nanoparticle Research, 2017, Vol.19 (4)
来源数据库: Springer Nature Journal
DOI: 10.1007/s11051-017-3781-2
关键词: Hydrothermal synthesisRed phosphorusOxyacidNickelNanometerHDS
英文摘要: Nanosized nickel phosphide (Ni2P) has been synthesized via hydrothermal reaction with environmental-friendly red phosphorus and nickel chloride. The reaction mechanism has been studied by measurement techniques of IC, XRD ,TEM, EDS, and XPS. The results showed that the particle sizes of as-prepared Ni2P are in nanoscale ranging from 10 to 30 nm. In hydrothermal reaction, red phosphorus reacts with water to its oxyacids, especially its hypophosphorous acid (or hypophosphite) which can reduce nickel chloride to nickel, and then metallic nickel will penetrate into the rest of red phosphorus to generate nano-Ni2P. Furthermore, the catalytic performance of as-synthesized Ni2P for the hydrodesulfurization of dibenzothiophene has been tested. It has...
原始语种摘要: Nanosized nickel phosphide (Ni2P) has been synthesized via hydrothermal reaction with environmental-friendly red phosphorus and nickel chloride. The reaction mechanism has been studied by measurement techniques of IC, XRD ,TEM, EDS, and XPS. The results showed that the particle sizes of as-prepared Ni2P are in nanoscale ranging from 10 to 30 nm. In hydrothermal reaction, red phosphorus reacts with water to its oxyacids, especially its hypophosphorous acid (or hypophosphite) which can reduce nickel chloride to nickel, and then metallic nickel will penetrate into the rest of red phosphorus to generate nano-Ni2P. Furthermore, the catalytic performance of as-synthesized Ni2P for the hydrodesulfurization of dibenzothiophene has been tested. It has...
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影响因子:2.175 (2012)

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关键词翻译
关键词翻译
  • nanoparticle 乳酸
  • synthesis 合成
  • hydrothermal 热液的
  • phosphorus 
  • reaction 反酌
  • hypophosphite 次磷酸盐
  • nickel 
  • catalytic 催化的
  • chloride 氯化物
  • process 过程