Phosphine oxide-Sc(OTf) 3 catalyzed enantioselective bromoaminocyclization of tri -substituted allyl N -tosylcarbamates
作者: Xiangyu TanHongjie PanHua TianYian Shi
作者单位: 1Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences
2University of Chinese Academy of Sciences
3Institute of Natural and Synthetic Organic Chemistry, Changzhou University
4Department of Chemistry, Colorado State University
刊名: Science China Chemistry, 2018, Vol.61 (6), pp.656-659
来源数据库: Springer Nature Journal
DOI: 10.1007/s11426-017-9192-x
关键词: Asymmetric bromonationBromoaminocyclizationPhosphine oxide-Sc(OTf)35-bromo-13-oxazinan-2-ones
原始语种摘要: Abstract(#br)Phosphine oxide-Sc(OTf) 3 catalyzed regio- and enantioselective bromoaminocyclization of tri -substituted allyl N -tosylcarbamates is described. A wide variety of optically active tertiary 5-bromo-1,3-oxazinan-2-ones can be obtained with high regio-and enantioselectivity.
全文获取路径: Springer Nature  (合作)
影响因子:1.327 (2012)