Polythiophene-block-poly(phenyl isocyanide) copolymers: One-pot synthesis, properties and applications
作者: Li ZhouZhi-qiang JiangLei XuNa LiuZong-quan Wu
作者单位: 1Hefei University of Technology
刊名: Chinese Journal of Polymer Science, 2017, Vol.35 (12), pp.1447-1456
来源数据库: Springer Journal
DOI: 10.1007/s10118-017-2003-9
关键词: Conjugated polymerHelical polymerPolyisocyanideBlock copolymerLiving polymerization
英文摘要: Conjugated block copolymers have gained increasing interests in recent years. Development of a novel method for facile synthesis of conjugated block copolymers with desired structures and functions is greatly desired. In this mini review, we summarized the recent advances in one-pot synthesis of conjugated block copolymers containing π -conjugated polythiophene and helical polyisocyanide segments by using a nickel(II) complex as single catalyst. The sequential living polymerization of the two monomers proceeded in a controlled manner, affording expected block copolymers in high yields with controlled molecular weights ( M ns) and narrow molecular weight distributions ( M w/ M ns). By using this method, a family of block copolymers with expected structure...
原始语种摘要: Conjugated block copolymers have gained increasing interests in recent years. Development of a novel method for facile synthesis of conjugated block copolymers with desired structures and functions is greatly desired. In this mini review, we summarized the recent advances in one-pot synthesis of conjugated block copolymers containing π -conjugated polythiophene and helical polyisocyanide segments by using a nickel(II) complex as single catalyst. The sequential living polymerization of the two monomers proceeded in a controlled manner, affording expected block copolymers in high yields with controlled molecular weights ( M ns) and narrow molecular weight distributions ( M w/ M ns). By using this method, a family of block copolymers with expected structure...
全文获取路径: Springer  (合作)
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来源刊物:
影响因子:1.27 (2012)

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关键词翻译
关键词翻译
  • 共轭的 预期
  • block 滑车
  • copolymers 共聚物
  • synthesis 合成
  • controlled 受控
  • polymerization 聚合酌
  • recent 近来的
  • isocyanide 异腈
  • tunable 可(协)调
  • expected 预期
  • conjugated 预期