A mild process for the synthesis of Na 2 Ti 3 O 7 as an anode material for sodium-ion batteries in deep eutectic solvent
作者: Cheng WangYang YangZongni ChenCui HeJing SuYanxuan Wen
作者单位: 1School of Chemistry and Chemical Engineering, Guangxi University
2School of Chemistry and Materials Science, Nanjing Normal University
刊名: Journal of Materials Science: Materials in Electronics, 2019, Vol.30 (9), pp.8422-8427
来源数据库: Springer Nature Journal
DOI: 10.1007/s10854-019-01159-6
原始语种摘要: Abstract(#br)Low capacity and poor cycle stability are two typical drawbacks of Na 2 Ti 3 O 7 when applied to the sodium-ion batteries as electrode materials. Here, we successfully synthesized Na 2 Ti 3 O 7 by a mild process in chloride/ethylene glycol-based deep eutectic solvent. The prepared Na 2 Ti 3 O 7 overcomes the above drawbacks of Na 2 Ti 3 O 7 which was synthesized by conventional methods. Our synthesized Na 2 Ti 3 O 7 can deliver discharge capacities of 127 mAh g −1 after 50 cycles and 72 mAh g −1 after 2000 cycles at current density of 1C and 5C, respectively. This cheap and environmentally friendly Na 2 Ti 3 O 7 exhibits excellent rate performance and cycling stability. In addition, we also further investigate the sodium storage mechanism of this product, the results show...
全文获取路径: Springer Nature  (合作)