Synthesis, crystal structures, and antibacterial activity of copper(II) and cobalt(III) complexes derived from 2-[(2-dimethylaminoethylimino)methyl]-4-methylphenol
作者: L. XueD. DengQ. Wang
作者单位: 1Third Affiliated Hospital of Soochow University
刊名: Russian Journal of Coordination Chemistry, 2017, Vol.43 (3), pp.181-188
来源数据库: Springer Journal
DOI: 10.1134/S107032841703006X
关键词: Schiff baseСopper(II) complexСobalt(III) complexX-ray diffractionHydrogen bondsAntibacterial activity
英文摘要: A new tetranuclear copper(II) complex ( I ) and a new mononuclear cobalt(III) complex ( II ) have been synthesized from the Schiff base compound 2-[(2-dimethylaminoethylimino)methyl]-4-methylphenol. The complexes have been characterized by physico-chemical and spectroscopic methods, as well as single crystal X-ray determination (CIF files CCDC nos. 1447778 (I) and 1447779 (II)). The Cu atoms in complex I are in square pyramidal coordination, and the Co atom in complex II is in octahedral coordination. Crystal structures of the complex are stabilized by hydrogen bonds and π···π interactions. The complexes and the Schiff base compound were assayed for antibacterial activities against three Gram-positive bacterial strains ( B. subtilis , S. aureus , and St. faecalis ) and three Gram-negative...
原始语种摘要: A new tetranuclear copper(II) complex ( I ) and a new mononuclear cobalt(III) complex ( II ) have been synthesized from the Schiff base compound 2-[(2-dimethylaminoethylimino)methyl]-4-methylphenol. The complexes have been characterized by physico-chemical and spectroscopic methods, as well as single crystal X-ray determination (CIF files CCDC nos. 1447778 (I) and 1447779 (II)). The Cu atoms in complex I are in square pyramidal coordination, and the Co atom in complex II is in octahedral coordination. Crystal structures of the complex are stabilized by hydrogen bonds and π···π interactions. The complexes and the Schiff base compound were assayed for antibacterial activities against three Gram-positive bacterial strains ( B. subtilis , S. aureus , and St. faecalis ) and three Gram-negative...
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影响因子:0.466 (2012)

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关键词翻译
关键词翻译
  • complex 超群
  • methylphenol 甲酚
  • crystal 晶体
  • activity 活度
  • coordination 配位
  • antibacterial 抗细菌的
  • diffraction 衍射
  • tetranuclear 四环的
  • bonds 公债
  • stabilized 稳定的