Investigation on Third-Order Nonlinear Optical Properties of Four Transition Metal Complexes Thin Films by Z-Scan Technique
作者: Zhaoxun LianKai JiangTianjun LouNing ZhaoPing LiuCaixia An
作者单位: 1Henan Institute of Science and Technology
2Henan Normal University
刊名: Journal of Cluster Science, 2017, Vol.28 (3), pp.1509-1521
来源数据库: Springer Nature Journal
DOI: 10.1007/s10876-017-1161-9
关键词: Terpyridine ligandsThird-order nonlinear opticsZ-scanTransition metalCrystal structure
原始语种摘要: In this work, four new transition metal complexes, [Zn(PTP)]12(1,4-NDA)12·2H2O ( 1) , [Zn(PTP) (4,4′-ODA)]2 ( 2 ), [Ni(PTP)(4,4′-ODA)]2 ( 3 ) and [Ni(FTP)]2Cl4 ( 4 ), have been synthesized by the reaction between a metal salt, Zn(II) or Ni(II), a rigid polycarboxylic ligand, naphthalene-1,4-dicarboxylic acid (1,4-NDA) or 4,4′-oxydibenzoic acid (4,4′-ODA) and a co-ligand, 4′-phenyl-2,2′:6′,2″-terpyridine (PTP) or 4′-(furan-2-yl)-2,2′:6′,2″-terpyridine (FTP). Complex 1 based on {Zn(PTP)(1,4-NDA)}n intertwined chains characterized by three different configurations which form a chiral chain structure. Complexes 2 and 3 present a structure made of discrete rings containing two central metal atoms. In...
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影响因子:1.111 (2012)

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关键词翻译
关键词翻译
  • third 第三的
  • nonlinear 非线性的
  • structure 构造
  • complex 超群
  • refractive 折射率
  • saturable 可饱和
  • FTP File Transfer Program
  • metal 金属
  • coefficient 系数
  • transition 转移