Syntheses, Crystal Structures, and Luminescence Properties of Co(II), Ni(II) and Zn(II) Complexes with 4′-(4-(Imidazol-1-Yl)phenyl)-2,2′:6′,2″-Terpyridine
作者: W. W. FuQ. HuangS. T. LiuW. J. WuJ. R. ShenS. H. Li
作者单位: 1Hengyang Normal University
刊名: Russian Journal of Coordination Chemistry, 2017, Vol.43 (10), pp.670-678
来源数据库: Springer Nature Journal
DOI: 10.1134/S1070328417100037
关键词: 4'-(4-(imidazol-1-yl)phenyl)-22':6'2″-terpyridineCo(II) complexNi(II) complexZn(II) complexCrystal structureLuminescence
原始语种摘要: Three coordination complexes [Co(Imphtpy)2]Cl2 · CHCl3 · 3H2O (I), [Ni(Imphtpy)2]Cl2 · CHCl3 · C2H5OH ( II ) and [Zn(Imphtpy)]Cl2 ( III ) (Imphtpy = 4'-(4-(imidazol-1-yl)phenyl)2,2':6',2″-terpyridine) have been synthesized and characterized by IR, elemental analysis and X-ray single crystal diffraction (СIF files CCDC nos. 1012055 ( I ), 1011708 ( II ), 1011709 (III)). Complexes I and II are isomorphism except for some solvent molecules. In the crystal, both face-to-face interactions between pyridyl ring, imidazole rings and phenyl rings and hydrogen bonds facilitate the construction of 3D networks. There are no hydrogen bonds in III and the packing of discrete neutral molecules...
全文获取路径: Springer Nature  (合作)
影响因子:0.466 (2012)

  •  Interactive Interface
  • phenyl 苯基
  • II Interactive Interface
  • Ni Interactive Interface
  • imidazole 咪唑
  • pyridyl 氮苯基
  • elemental 元素的
  • bonds 公债
  • complex 超群
  • rings 泥包
  • hydrogen