A novel dinuclear Cu II complex based on flexible bis(triazole): Synthesis, structure and physical properties
作者: X.-J. XuX. FangH.-N. YuZ. ZhouJ. Wang
作者单位: 1Yancheng Teachers University
刊名: Journal of Structural Chemistry, 2017, Vol.58 (7), pp.1440-1442
来源数据库: Springer Nature Journal
DOI: 10.1134/S0022476617070241
关键词: Cu(II) complex11′-(22′-oxybis(ethane-21-diyl))bis(1H-124-triazole)DinuclearPhotocatalytic activity
英文摘要: New dinuclear copper(II) complex [Cu2(BTE)2(N3)4] ( 1 ) (BTE = 1,1′-(2,2′-oxybis(ethane-2,1-diyl))bis(1H-1,2,4-triazole)) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. Single crystal X-ray diffraction reveals that complex 1 is a centrosymmetric dinuclear Cu(II) cluster unit with a Cu–Cu separation of 3.267(6) Å. In addition, complex 1 exhibits a high photocatalytic degradation activity for the degradation of rhodamine B.
原始语种摘要: New dinuclear copper(II) complex [Cu2(BTE)2(N3)4] ( 1 ) (BTE = 1,1′-(2,2′-oxybis(ethane-2,1-diyl))bis(1H-1,2,4-triazole)) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. Single crystal X-ray diffraction reveals that complex 1 is a centrosymmetric dinuclear Cu(II) cluster unit with a Cu–Cu separation of 3.267(6) Å. In addition, complex 1 exhibits a high photocatalytic degradation activity for the degradation of rhodamine B.
全文获取路径: Springer Nature  (合作)
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影响因子:0.575 (2012)

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关键词翻译
关键词翻译
  • dinuclear 二核的
  • triazole 三唑
  • complex 超群
  • ethane 乙烷
  • elemental 元素的
  • structure 构造
  • diffraction 衍射
  • degradation 减嚣夷酌
  • crystal 晶体
  • activity 活度