Exploration of Zr–Metal–Organic Framework as Efficient Photocatalyst for Hydrogen Production
作者: Zhiliang JinHao Yang
作者单位: 1North Minzu University
刊名: Nanoscale Research Letters, 2017, Vol.12 (1)
来源数据库: Springer Nature Journal
DOI: 10.1186/s11671-017-2311-6
关键词: Zr–metal–organic frameworkUiO-66Hydrogen productionPhotocatalyst
英文摘要: The application of metal–organic framework (MOF) in the field of photocatalysis is limited, because of its unstable chemical properties and failure to respond in visible light. Herein, the Pd/MOF catalysts were prepared by impregnation reduction. It is important that we have reasonably constructed the dye-sensitized system of Pd/MOF and successfully extended the application of MOF to the visible range. It exhibited maximal photocatalytic activity (9.43 mmol/g) under visible-light irradiation ( λ ≥ 420 nm) with eosin Y as a photo-sensitizer, which was enhanced twice the order of magnitude compared with the pure MOF (0.03 mmol/g). The activation process with an exchangeable guest solvent produced the Zr–MOF with the high surface area and the high stability, which provide a great electronic...
原始语种摘要: The application of metal–organic framework (MOF) in the field of photocatalysis is limited, because of its unstable chemical properties and failure to respond in visible light. Herein, the Pd/MOF catalysts were prepared by impregnation reduction. It is important that we have reasonably constructed the dye-sensitized system of Pd/MOF and successfully extended the application of MOF to the visible range. It exhibited maximal photocatalytic activity (9.43 mmol/g) under visible-light irradiation ( λ ≥ 420 nm) with eosin Y as a photo-sensitizer, which was enhanced twice the order of magnitude compared with the pure MOF (0.03 mmol/g). The activation process with an exchangeable guest solvent produced the Zr–MOF with the high surface area and the high stability, which provide a great electronic...
全文获取路径: Springer Nature  (合作)
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来源刊物:
影响因子:2.524 (2012)

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关键词翻译
关键词翻译
  • reference 基准电压源
  • production 生产
  • successfully 成功地
  • provide 规定
  • electronic 电子的
  • photocatalysis 光催化酌
  • great 大的
  • visible 看得见的
  • range 射程
  • process 过程