Synthesis of star polymeric ionic liquids and use as the stabilizers for high internal phase emulsions
作者: Qi-jing ChenZe-sheng An
作者单位: 1Shanghai University
刊名: Chinese Journal of Polymer Science, 2017, Vol.35 (1), pp.54-65
来源数据库: Springer Nature Journal
DOI: 10.1007/s10118-016-1858-5
关键词: Star polymersPoly(ionic liquids)Emulsions
英文摘要: A series of well-defined core cross-linked star (CCS) polymeric ionic liquids (PILs) were synthesized via a three-step approach. First, the styrenic imidazole-based CCS polymer (S-PVBnIm) was prepared by the RAFT-mediated heterogeneous polymerization in a water/ethanol solution, followed by the quaternization of S-PVBnIm with bromoalkanes and anion exchange. The CCS polymers were characterized by gel permeation chromatography (GPC), nuclear magnetic resonance (NMR) spectroscopy, Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA), and differential scanning calorimetry (DSC). The obtained CCS polymers were used as the effective emulsifiers for oil-in-water high internal phase emulsions (HIPEs). Multiple oils with different polarity including n -dodecane,...
原始语种摘要: A series of well-defined core cross-linked star (CCS) polymeric ionic liquids (PILs) were synthesized via a three-step approach. First, the styrenic imidazole-based CCS polymer (S-PVBnIm) was prepared by the RAFT-mediated heterogeneous polymerization in a water/ethanol solution, followed by the quaternization of S-PVBnIm with bromoalkanes and anion exchange. The CCS polymers were characterized by gel permeation chromatography (GPC), nuclear magnetic resonance (NMR) spectroscopy, Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA), and differential scanning calorimetry (DSC). The obtained CCS polymers were used as the effective emulsifiers for oil-in-water high internal phase emulsions (HIPEs). Multiple oils with different polarity including n -dodecane,...
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影响因子:1.27 (2012)

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关键词翻译
关键词翻译
  • polymeric 聚合的
  • ionic 离子的
  • liquids 液体
  • phase 相位
  • stabilize 稳定
  • emulsions 乳剂
  • imidazole 咪唑
  • intriguing 引起兴趣的
  • gravimetric 重力的
  • internal 内部的