Convenient Synthesis of 1-(Trimethylsilyl)- and 1-(Trimethylstannyl)vinylphosphonates
作者: Yoshiharu OkadaTomohiro MaruyamaShin-ichi TamuraHirohito KameokaSatoshi MasudaYuichiro TokudaJunya SakaiMasato Nomura
作者单位: 1Department of Biotechnology and Chemistry, Faculty of Engineering , Kinki University , Umenobe 1, Takaya , 739-2116 , Higashi-Hiroshima , Japan
刊名: Phosphorus, Sulfur, and Silicon and the Related Elements, 2014, Vol.189 (6), pp.778-790
来源数据库: Taylor & Francis Journal
DOI: 10.1080/10426507.2013.855765
关键词: VinylphosphonatesvinylsilanesPeterson reaction
原始语种摘要: Abstract(#br)Dimethyl 1,1-bis(trimethylsilyl)methylphosphonate and dimethyl 1-(trimethylsilyl)-1-(trimethylstannyl)methylphosphonate were succeeded to react with aromatic aldehydes in the presence of methyl benzoate as additive to give the corresponding vinylphosphonates in moderate yields.
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