Synthesis of 1H-Diphosphirene, Phosphorus-Carbon Cage and 2,3-Dihydro-1,2,3-Triphosphete Tungsten Complexes
作者: Udo RohdeHendrik WilkensRainer Streubel
刊名: Phosphorus, Sulfur, and Silicon and the Related Elements, 1997, Vol.124 (1), pp.545-548
来源数据库: Taylor & Francis Journal
DOI: 10.1080/10426509708545680
关键词: phosphorus heterocycles2 H -azaphosphirene complexesl H -diphosphirene complexes23-dihydro-123-triphosphete complexesphosphorus-carbon cage compounds
原始语种摘要: New lH-diphosphirene and 2,3-dihydro-l,2,3-triphosphete tungsten complexes have been synthesized, by thermal decomposition of different 2H-azaphosphirene complexes in the presence of various phosphaalkynes. Novel phosphorus-carbon cage complexes were obtained, if a pentamethylcyclopentadienyl-substituted 2H-azaphosphirene complex and alkyl-substituted phosphaalkynes were employed.
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