Synthesis, characterization and anticancer studies of bis-(N-methyl-1-phenyldithiocarbamato) Cu(II), Zn(II), and Pt(II) complexes: single crystal X-ray structure of the copper complex
作者: Fartisincha P. AndrewPeter A. Ajibade
作者单位: 1School of Chemistry and Physics , University of KwaZulu-Natal , Scottsville , Pietermaritzburg , South Africa
刊名: Journal of Coordination Chemistry, 2018, Vol.71 (16-18), pp.2776-2786
来源数据库: Taylor & Francis Journal
DOI: 10.1080/00958972.2018.1489537
关键词: DithiocarbamatesMetal complexesSynthesisCrystal structureAnticancer
原始语种摘要: Abstract(#br)Cu(II), Pt(II), and Zn(II) complexes of N-methyl-1-phenyldithiocarbamate were synthesized and characterized by FTIR, NMR, UV-visible spectroscopy and elemental analysis. The complexes were formulated as [Cu(L)2], [Zn(L)2] and [Pt(L)2] (where L = N-methyl-1-phenyldithio­carbamate) in which two molecules of the ligands coordinate to the metal ions in a bidentate chelating fashion. This is confirmed by elemental analysis and the presence of strong single bands at 952, 951, and 955 cm−1 for Cu(II), Pt(II), and Zn(II) complexes, respectively, in the FTIR spectra. The electronic spectra of Pt(II) and Cu(II) complexes are consistent with four-coordinate square planar geometry. Single crystal X-ray of [Cu(N-mpDTC)2] confirmed...
全文获取路径: Taylor & Francis  (合作)
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影响因子:1.801 (2012)

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关键词翻译
关键词翻译
  • Interactive Interface 元素锌的符号
  • complexes 联合企业
  • Cu 
  • Zn 元素锌的符号
  • II 元素锌的符号
  • methyl 甲基
  • elemental 元素的
  • intramolecular 分子内的
  • structure 构造
  • bonded 保税
  • chelating 螯合