ReviewInverse coordination. Organic nitrogen heterocycles as coordination centers. A survey of molecular topologies and systematization. Part 1. Five-membered and smaller rings
作者: Ionel Haiduc
作者单位: 1Facultatea de Chimie , Universitatea Babeş-Bolyai , Cluj-Napoca , Romania
刊名: Journal of Coordination Chemistry, 2019, Vol.72 (13), pp.2127-2159
来源数据库: Taylor & Francis Journal
DOI: 10.1080/00958972.2019.1641702
关键词: Inverse coordinationMetal complexesMolecular topologyNitrogen heterocyclePyrazoleImidazoleTriazoleTetrazolePyrroleOxadiazoleThiadiazoleDiazaphospholeDiazirineDiazete
原始语种摘要: Abstract(#br)This review continues the previous articles (I. Haiduc, J. Coord. Chem ., 71(#br), 3139 (2018) and J. Coord. Chem ., 72(#br), 35 (2019)), which discussed the structures with nitrogen-donor species (atoms and molecules) acting as centers in inverse coordination complexes. i.e. metal compounds which display an arrangement of acceptor and donor sites opposite to that occurring in conventional coordination complexes. This review is Part 1 of a work which introduces the topology of inverse coordination complexes with organic nitrogen heterocycles, and presents a panorama of five-membered rings and covers pyrazole, imidazole, triazoles, tetrazole, pyrrole, oxadiazole, thiadiazole, azaphospholes, and smaller rings.
全文获取路径: Taylor & Francis  (合作)
影响因子:1.801 (2012)

  • 收体 给予体
  • coordination 配位
  • centers 机组间距
  • membered 有肢的
  • nitrogen 
  • rings 泥包
  • molecular 分子的
  • panorama 全景图
  • heterocycle 杂环
  • donor 给予体
  • acceptor 给予体