Synthesis, characterization, crystal structure, and electrochemical properties of three copper(II) complexes with 3,5-dihalosalicylaldehyde Schiff bases derived from amantadine
作者: Xu-Dong JinHan WangXiao-Kang XieJia-Yue SunHe-Ming Liang
作者单位: 1College of Chemistry , Liaoning University , Shenyang , People’s Republic of China
刊名: Journal of Coordination Chemistry, 2019, Vol.72 (14), pp.2295-2309
来源数据库: Taylor & Francis Journal
DOI: 10.1080/00958972.2019.1655643
关键词: Copper(II) complexAmantadine35-dihalosalicylaldehyde Schiff baseSynthesisCrystal structureElectrochemical property
原始语种摘要: Abstract(#br)Complexes 1(#br)-3(#br), C34H36X4CuN2O2 (X = Cl, Br, I), were synthesized with copper chloride dihydrate and three new Schiff base ligands derived from amantadine and 3,5-dihalosalicylaldehydes. They were characterized by IR, UV–VIS, elemental analysis, molar conductance, and single-crystal X-ray diffraction. Single-crystal X-ray diffraction analysis reveals that 1(#br) and 2(#br) crystallize in the triclinic system, P ī space group. Each asymmetric unit consists of one copper(II) ion, two corresponding deprotonated Schiff base ligands and one lattice dichloromethane molecule. 3(#br) crystallizes in the monoclinic system, P 21/ n space group. Each asymmetric unit consists of one copper(II) ion and two...
全文获取路径: Taylor & Francis  (合作)
影响因子:1.801 (2012)

  • II Interactive Interface
  • tetrahedral 四面的
  • crystal 晶体
  • complexes 联合企业
  • structure 构造
  • elemental 元素的
  • asymmetric 不对称的
  • monoclinic 单钭的
  • copper 
  • distorted