Silica Triflate as an Efficient Reagent for the Chemoselective Formylation of Alcohols
作者: Farhad ShiriniKatayoun MarjaniHossein Taherpour NahzomiMohammad Ali Zolfigol
作者单位: 1Department of Chemistry, Guilan University, Rasht, Iran
2College of Chemistry, Teacher Training University, Tehran, Iran
3Department of Chemistry, Guilan University, Rasht, Iran,Teacher Training University, Iran
4Department of Chemistry, Bu-Ali Sina University, Hamadan, Iran
刊名: Phosphorus, Sulfur, and Silicon and the Related Elements, 2007, Vol.182 (6), pp.1245-1251
来源数据库: Taylor & Francis Journal
DOI: 10.1080/10426500601160710
关键词: Formylationheterogeneous reaction conditionssilica triflatesilica geltrifluoromethane sulfonyl chloride
原始语种摘要: Silica triflate, as a new and stable silica-based reagent, is prepared by a reaction of silica gel with trifluoromethane sulfonyl chloride at room temperature. This reagent can be used for the efficient and selective formylation of alcohols in the presence of phenols in a relatively short reaction time and high yields under heterogeneous reaction conditions.
全文获取路径: Taylor & Francis  (合作)