Synthesis and characterization of an anion triazole framework containing μ3-Cl and μ2-Cl bridges
作者: Yuan Yuan LiuBin DingEn-Cui YangXiao-Jun ZhaoXiu Guang Wang
作者单位: 1College of Chemistry and Life Chemistry, Tianjin Normal University, Tianjin 300387, PR China
刊名: Journal of Coordination Chemistry, 2009, Vol.62 (10), pp.1623-1629
来源数据库: Taylor & Francis Journal
DOI: 10.1080/00958970802680690
关键词: 35-Dimethyl-4-amino-124-triazoleμ3-Clμ2-ClAnion chainsFluorescence
原始语种摘要: Using 3,5-dimethyl-4-amino-1,2,4-triazole (L) and corresponding Ag(I), K(I) salts under ammonia solution and hydrothermal conditions, a triazole-silver(I)-potassium(I) complex {K[Ag2L2(μ3-Cl)(μ2-Cl)2]}n (1) has been isolated. In 1, μ3-Cl, μ2-Cl and L bridge AgI ions forming a rare 1-D [Ag2L2(μ3-Cl)(μ2-Cl)2]- anion while K+ cations are located between neighboring anion chains. Strong solid-state fluorescence spectrum of 1 was also investigated showing that the excited peak is located at 320 nm while the maximum emission peak is located at 440 nm.
全文获取路径: Taylor & Francis  (合作)
影响因子:1.801 (2012)