Dual Detection Highly Selective Colorimetric Chemosensors for Fluoride and Copper(II) Ions Based on Imine-Phenol Derivative
作者: Phoomirut Nusuwan Piyada Jittangprasert Mayuso Kuno Kem Pumsa-ardPan Tongraung
刊名: Asian Journal of Chemistry, 2020, Vol.32 (4)
来源数据库: Asian Journal of Chemistry
DOI: 10.14233/ajchem.2020.22442
关键词: Dual detectionColorimetric chemosensorCu2+ and F–Computational chemistry.
原始语种摘要: A simple dual detection using colorimetric chemosensor, imine-phenol derivative L (bearing a 2-iminephenol group as a binding unit and a-nitrophenylazo group as a signaling unit), were synthesized for a high yield in two simple steps. Complexations of chemosensor L with various anions in acetonitrile solvent and other metal ions in DMSO/H2O solvent were monitored by UV-visible spectroscopy. The results indicated that the chemosensor L showed high selectivity for F− and Cu2+ ions. Furthermore, the complexes for L-F− and L-Cu2+ were evaluated by computational chemistry using a B3LYP/6-31G (d,p) and a B3LYP/6-311G (d,p) level of calculation. The complexes between L with F− and Cu2+ were magenta and yellow colored, respectively. Chemosensor L can be applied for the analysis of F− and Cu2+...
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关键词翻译
关键词翻译
  • II Interactive Interface
  • computational 计算的
  • colour 颜料
  • colored 有色的
  • magenta 品红色
  • simple 单纯的
  • solvent 溶媒
  • detection 探测
  • visible 看得见的
  • making 制定