1,3-Ninhydrin dihydrazone featuring an R 4 <sup>4</sup>(12) motif with \bf \overline{4} symmetry and comprising only N and H atoms
作者: Alexander J. BlakeYonas ChebudeHaregewine TadesseBerhanu Wondimu
作者单位: 1School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, England
2Department of Chemistry, Addis Ababa University, PO Box 1176, Addis Ababa, Ethiopia
刊名: Acta Crystallogr C Cryst Struct Commun, 2012, Vol.68 (Pt 9), pp.o362-o364
来源数据库: International Union of Crystallography
DOI: 10.1107/S0108270112034749
原始语种摘要: In the title compound [systematic name: (1Z,3Z)-1,3-dihydrazinylidene-1H-inden-2(3H)-one], C 9 H 8 N 4 O, isolated molecules possess approximate noncrystallographic C 2v symmetry and their cis conformation and planarity are assisted by a pair of short intramolecular N—H...O hydrogen bonds. Each molecule is asymmetrically involved in an extensive three-dimensional network of N—H...O and N—H...N hydrogen bonds, and the structure also exhibits weaker π–π and C=O...C interactions. The structure features an R 4 4(12) motif consisting solely of N and H atoms and possessing crystallographic \overline{4} symmetry.
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关键词翻译
关键词翻译
  • dihydrazone 二腙
  • bf 黑体
  • symmetry 对称
  • intramolecular 分子内的
  • bonds 公债
  • planarity 平面度
  • conformation 构象
  • asymmetrically 不对称地
  • systematic 有系统的
  • structure 构造