Efficient Synthesis of (E)-Vinylgermanes via Stille Cross-CouplingReaction from 1-Tributylstannyl-2-trialkyl(triphenyl)germylethylenes
作者: Franck David-QuillotDidier MarsacqAlexia BallandJérôme ThibonnetMohamed AbarbriAlain Duchêne
刊名: Synthesis, 2003, Vol.2003 (3), pp.0448-0454
来源数据库: Thieme Journal
DOI: 10.1055/s-2003-37358
关键词: coupling reactionsorganogermanium compoundspalladiumcatalyst
原始语种摘要: The transfer of a β-vinylgermyl synthon is easily achievedby Stille reaction using ( E)-1-tributylstannyl-2-trialkyl(or triphenyl)germylethylenes.With this methodology good yields of ( E)-arylor heteroarylvinylgermanes, stereodefined germyldienoic acids, andgermyl α,β-enones are obtained from acid chlorides.
全文获取路径: Thieme 
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影响因子:2.5 (2012)

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关键词翻译
关键词翻译
  • trialkyl 三烷基
  • triphenyl 三苯基