Hydrogen at Electrochemical Interfaces
作者: Osamu Sugino
刊名: Journal of the Physical Society of Japan, 2020, Vol.89 (5)
来源数据库: The physical Society of Japan
DOI: 10.7566/JPSJ.89.051013
原始语种摘要: At the electrode–electrolyte interface, hydrogen shows peculiar behavior being influenced by the dipole layer called Helmholtz layer. For the understanding of this system, first-principles methods have been intensively developed and applied to the benchmarking interface like Pt(111)-water; however, controversy still exists even on the hydrogen adsorption although being the simplest and most-studied problem. After giving introductory explanation of the electrochemical interface and reaction, we briefly review the advance of the theory. It has been revealed that the typical density functional calculations are occasionally not accurate enough and need to advance the description of electron correlation and nuclear quantum effect. The advanced calculation shows a promise of elucidating some...
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  • promise 允诺
  • benchmarking 基准测试
  • providing 只要
  • advance 前进
  • still 
  • system 
  • developed 开发
  • peculiar 独特的
  • therewith 与此
  • explanation 说明